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RAS Chemistry & Material ScienceМембраны и мембранные технологии Membranes and Membrane Technologies

  • ISSN (Print) 2218-1172
  • ISSN (Online) 2218-1180

Ion Transport Asymmetry in Hybrid Membranes MF-4SK with Gradient Distribution of Hydrated Silicon Oxide, Including Modified Surface

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PII
S2218118025010021-1
DOI
10.7868/S2218118025010021
Publication type
Article
Status
Published
Authors
E. Yu. Safronova
  • Affiliation: N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Volume/ Edition
Volume 15 / Issue number 1
Pages
22-32
Abstract
The paper presents the results of investigation of properties of hybrid materials based on homogeneous membrane MF-4SC with gradient distribution of dopant along the thickness. Hydrated silicon oxide nanoparticles, including those with a functionalized surface containing proton acceptor groups, were used as dopant. The presence of asymmetry of diffusion permeability of HCl and NaCl solutions of the studied membranes was revealed. It is shown that the diffusion permeability depends on the orientation of the membrane with respect to the electrolyte solution and the asymmetry reaches 65%. Depending on the surface properties of the introduced silicon oxide (on the nature and size of grafted groups) the direction of preferential ion transport changes. The causes of the diffusion permeability asymmetry and factors determining its direction are described.
Keywords
гибридные мембраны ионный транспорт асимметрия ионного транспорта диффузионная проницаемость
Date of publication
29.12.2025
Year of publication
2025
Number of purchasers
0
Views
58

References

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