ОХНММембраны и мембранные технологии Membranes and Membrane Technologies

  • ISSN (Print) 2218-1172
  • ISSN (Online) 2218-1180

Стабильность полимерных композиционных мембран на основе фторсодержащих полисилоксанов в условиях тропического климата

Код статьи
S2218117225010044-1
DOI
10.31857/S2218117225010044
Тип публикации
Статья
Статус публикации
Опубликовано
Авторы
Том/ Выпуск
Том 15 / Номер выпуска 1
Страницы
44-62
Аннотация
Одной из ключевых задач мембранной технологии является повышение устойчивости к засорению (фаулингу) и деградации поверхности мембран. В данной работе исследована стабильность свойств селективного слоя на основе фторсодержащих полисилоксанов при экспозиции в течение 6 месяцев на климатических площадках Вьетнама. В работе исследованы три композиционные мембраны на микрофильтрационной подложке МФФК-1 с селективными слоями: 1) полидециметилсилоксана (С10), 2) сополимера С10 и полисилоксана с трифторалкилакрилатной боковой группой (С10–F3), 3) сополимера С10 и полисилоксана с перфтороктильной боковой группой (С10–ПФО). Проанализировано сравнение изменения состава и свойств поверхности селективного слоя, а также газотранспортных свойств до и после экспозиции на испытательных площадках. Показано, что для мембран на основе фторсодержащих полисилоксанов (С10–F3 и С10–ПФО) наблюдается меньшее засорение и деградация полимера селективного слоя. Для образца С10 отмечено разрушение боковых алкильных фрагментов и повышение концентрации атомов кислорода на поверхности селективного слоя, в том числе за счет осаждения микроводорослей. Мембраны С10–F3 продемонстрировали наибольшую стабильность газопроницаемости по СО2 и N2 (изменение не более 10%) и наименьшую окислительную деструкцию.
Ключевые слова
композиционные мембраны фторсодержащие полисилоксаны засорение климатические испытания в тропических условиях
Дата публикации
02.11.2025
Год выхода
2025
Всего подписок
0
Всего просмотров
75

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